Direct conversion of glucose to 5-hydroxymethylfurfural using a mixture of niobic acid and niobium phosphate as a solid acid catalyst

Citation data:

Fuel, ISSN: 0016-2361, Vol: 210, Page: 67-74

Publication Year:
Usage 9
Abstract Views 8
Link-outs 1
Captures 25
Readers 25
Social Media 100
Shares, Likes & Comments 98
Tweets 2
Citations 12
Citation Indexes 12
Mariana N. Catrinck; Emerson S. Ribeiro; Robson S. Monteiro; Rogério M. Ribas; Márcio H.P. Barbosa; Reinaldo F. Teófilo
Elsevier BV
Chemical Engineering; Energy; Chemistry
Most Recent Tweet View All Tweets
article description
The aim of this work was to optimize the acid-catalyzed conversion of glucose into 5-hydroxymethylfurfural (HMF) in an aqueous medium using niobic acid (NbO), niobium phosphate (NbP) and a mixture of both solid acid catalysts. A simplex-centroid mixture design was applied to optimize the mixture ratio between NbO and NbP. A central composite design was applied to process optimization. The studied variables were temperature (T), time (t) and substrate to catalyst weight ratio (R S/C ). The mixture design revealed excellent glucose conversion (55%) and HMF selectivity (56%) when the weight ratio between NbO and NbP was equal to 1:1. The experimental results demonstrate that a mixture of both solid acids provides a better combination of Brønsted and Lewis acidity for effective glucose dehydration into HMF than each individual catalyst.