Facile synthesis and characterization of highly fluorescent and biocompatible N-acetyl-L-cysteine capped CdTe/CdS/ZnS core/shell/shell quantum dots in aqueous phase.

Citation data:

Nanotechnology, ISSN: 1361-6528, Vol: 23, Issue: 49, Page: 495717

Publication Year:
2012
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Repository URL:
http://repository.hkbu.edu.hk/hkbu_staff_publication/2439
PMID:
23165590
DOI:
10.1088/0957-4484/23/49/495717
Author(s):
Xiao, Qi, Huang, Shan, Su, Wei, Chan, W. H., Liu, Yi
Publisher(s):
IOP publishing, IOP Publishing
Tags:
Chemical Engineering, Chemistry, Materials Science, Engineering
article description
The synthesis of water-soluble quantum dots (QDs) in aqueous phase has received much attention recently. To date various kinds of QDs such as CdTe, CdSe, CdTe/CdS and CdSe/ZnS have been synthesized by aqueous methods. However, generally poor-quality QDs (photoluminescent quantum yield (PLQY) lower than 30%) are obtained via this method and the 3-mercaptopropionic acid stabilizer is notorious for its toxicity and awful odor. Here we introduce a novel thiol ligand, N-acetyl-L-cysteine, as an ideal stabilizer that is successfully employed to synthesize high-quality CdTe/CdS/ZnS QDs via a simple aqueous phase. The core/shell/shell structures of the CdTe/CdS/ZnS QDs were verified by x-ray photoelectron spectroscopy, energy dispersive x-ray spectroscopy, x-ray powder diffraction and transmission electron microscopy. These QDs not only possess a high PLQY but also have excellent photostability and favorable biocompatibility, which is vital for many biological applications. This type of water-dispersed QD is a promising candidate for fluorescent probes in biological and medical fields.

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