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Manganese-Catalyzed Hydrocarbofunctionalization of Internal Alkenes

Chinese Journal of Chemistry, ISSN: 1614-7065, Vol: 38, Issue: 12, Page: 1497-1502
2020
  • 23
    Citations
  • 0
    Usage
  • 6
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    23
    • Citation Indexes
      23
  • Captures
    6

Article Description

A highly regio- and chemo-selective dimeric Mn(I)-catalyzed hydroarylation and hydroalkenylation of unbiased internal alkenes with commercially abundant organoboron compounds is reported. A wide range of densely functionalized aliphatic alkenyl amides can successfully undergo site-exclusive hydrocarbofunctionalization in air atmosphere without any exogenous directing auxiliary, affording an enhanced lead library of structurally diverse γ-functionalized carboxylic acid derivatives in moderate to good yields. The precise chemoselectivity of the reaction among multiple alkene units even in the presence of reactive terminal alkenes highlights the unique catalytic features of manganese catalyst, and the excellent functional group compatibility of primary amides further complements other transition metals.

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