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Microscopein situ FTIRS studies of CO adsorption on an array of platinum microelectrodes

Chinese Science Bulletin, ISSN: 1001-6538, Vol: 46, Issue: 19, Page: 1612-1614
2001
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  • Citations
    8
    • Citation Indexes
      8

Article Description

An array of platinum microelectrodes was designed and fabricated. The adsorption of CO on such a Pt microelectrode (μ-Pt) was investigated by employing microscope in situ FTIR spectroscopy. A nanostructured film is formed at the surface of μ-Pt (denoted as μ-Pt(R)) when it has been subjected to a treatment of fast potential cycling. Abnormal infrared effects (AIREs) were observed in CO adsorption on the surface of μ-Pt(R), consisting of the inversion of the IR bipolar CO band and the extensively enhanced IR adsorption of CO species.

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