Diruthenium(II,II) tetrakis(acetate) as a catalyst of choice for intermolecular insertion of stabilized diazocompounds into OH bonds
Tetrahedron Letters, ISSN: 0040-4039, Vol: 43, Issue: 20, Page: 3637-3640
2002
- 21Citations
- 13Captures
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Article Description
In the presence of 3 mol% of [Ru(OAc) 2 ] 2 at 90°C in hexafluorobenzene or alcohols as solvents the highly stabilized diazocoumarin 1 undergoes insertion into the OH bond of alcohols (and phenols) regio- and chemoselectively, affording the corresponding 3-alkoxy-4-hydroxycoumarin in moderate to excellent yields.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0040403902006184; http://dx.doi.org/10.1016/s0040-4039(02)00618-4; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0037071185&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0040403902006184; https://api.elsevier.com/content/article/PII:S0040403902006184?httpAccept=text/xml; https://api.elsevier.com/content/article/PII:S0040403902006184?httpAccept=text/plain; http://linkinghub.elsevier.com/retrieve/pii/S0040403902006184; http://api.elsevier.com/content/article/PII:S0040403902006184?httpAccept=text/xml; http://api.elsevier.com/content/article/PII:S0040403902006184?httpAccept=text/plain; http://dx.doi.org/10.1016/s0040-4039%2802%2900618-4; https://dx.doi.org/10.1016/s0040-4039%2802%2900618-4
Elsevier BV
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