Pyrene-Containing ortho -Oligo(phenylene)ethynylene Foldamer as a Ratiometric Probe Based on Circularly Polarized Luminescence
Journal of Organic Chemistry, ISSN: 1520-6904, Vol: 83, Issue: 8, Page: 4455-4463
2018
- 67Citations
- 42Captures
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Metrics Details
- Citations67
- Citation Indexes67
- CrossRef67
- 67
- Captures42
- Readers42
- 42
Article Description
In this manuscript, we report the first synthesis of an organic monomolecular emitter, which behaves as a circularly polarized luminescence (CPL)-based ratiometric probe. The enantiopure helical ortho-oligo(phenylene)ethynylene (o-OPE) core has been prepared by a new and efficient macrocyclization reaction. The combination of such o-OPE helical skeleton and a pyrene couple leads to two different CPL emission features in a single structure whose ratio linearly responds to silver(I) concentration.
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