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Detailed structure analysis of atomic positions and defects in zirconium metal-organic frameworks

Crystal Growth and Design, ISSN: 1528-7505, Vol: 14, Issue: 11, Page: 5370-5372
2014
  • 328
    Citations
  • 0
    Usage
  • 465
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    328
    • Citation Indexes
      328
  • Captures
    465

Article Description

We report the structure of the Zr metal-organic frameworks (MOFs) UiO-66 and UiO-67 to very fine detail using synchrotron single-crystal X-ray diffraction and the synthesis method used to obtain single crystals. Zr terephthalate MOF UiO-66 is known to have missing linkers, and the nature of these are shown to be coordinating water and solvent molecules. Single crystals of the isoreticular material UiO-67 does not show such missing linker defects. (Figure Presented).

Bibliographic Details

Sigurd Øien; David Wragg; Helge Reinsch; Stian Svelle; Silvia Bordiga; Karl Petter Lillerud; Carlo Lamberti

American Chemical Society (ACS)

Chemistry; Materials Science; Physics and Astronomy

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