Pd-catalyzed intramolecular C-N bond cleavage, 1,4-migration, spC-H activation, and Heck reaction: Four controllable diverse pathways depending on the judicious choice of the base and ligand
Journal of the American Chemical Society, ISSN: 1520-5126, Vol: 137, Issue: 3, Page: 1341-1347
2015
- 143Citations
- 60Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Metrics Details
- Citations143
- Citation Indexes143
- 143
- CrossRef142
- Captures60
- Readers60
- 60
Article Description
Diverse and controllable pathways induced by palladium-catalyzed intramolecular Heck reaction of N-vinylacetamides for the synthesis of nitrogen-containing products in reasonable to high yields via tuning the phosphine ligands and bases are reported. Domino reactions including unique β-N - Pd elimination, 1,4-Pd migration, or direct acyl C - H bond functionalization were found to be involved forming different products, respectively. Given the ability of using the same starting material to generate diverse products via completely different chemoselective processes, these current methodologies offer straightforward access to valuable nitrogencontaining products under mild reaction conditions as well as inspire the discovery of novel reactions. (Chemical Equation Presented).
Bibliographic Details
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