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A new entry in catalytic alkynylation of aldehydes and ketones: Dual activation of soft nucleophiles and hard electrophiles by an indium(III) catalyst

Organic Letters, ISSN: 1523-7060, Vol: 7, Issue: 7, Page: 1363-1366
2005
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Article Description

(Chemical Equation Presented). A new entry in catalytic alkynylation of carbonyl compounds was developed in which dual activation of both soft nucleophiles (terminal alkynes) and hard electrophiles (aldehydes and ketones) is achieved using an indium(III) catalyst. Preliminary mechanistic studies using in situ IR and NMR spectroscopic analysis are also discussed. © 2005 American Chemical Society.

Bibliographic Details

Takita, Ryo; Fukuta, Yuhei; Tsuji, Riichiro; Ohshima, Takashi; Shibasaki, Masakatsu

American Chemical Society (ACS)

Biochemistry, Genetics and Molecular Biology; Chemistry

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