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Two alternative, convenient routes to bis(diphenylacetylene)platinum(0)

Organometallics, ISSN: 0276-7333, Vol: 21, Issue: 18, Page: 3817-3818
2002
  • 17
    Citations
  • 0
    Usage
  • 10
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    17
    • Citation Indexes
      17
  • Captures
    10

Article Description

Two new synthetic routes are presented that allow the convenient preparation and isolation of bis-(diphenylacetylene)platinum(0) under ambient conditions. The first procedure is based on a ligand exchange reaction between Ph-C≡C-Ph and tris(styrene)platinum(0). The second framework relies on the reduction of cis-[PtCl(PhCH=CH)] with triphenylsilane in the presence of diphenylacetylene.

Bibliographic Details

Christian Huber; Walter R. Caseri; Akshay Kokil; Christoph Weder

American Chemical Society (ACS)

Chemistry

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