Efficient iridium-catalyzed decarbonylation reaction of aliphatic carboxylic acids leading to internal or terminal alkenes
Organometallics, ISSN: 0276-7333, Vol: 30, Issue: 6, Page: 1389-1394
2011
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Article Description
Vaska's complex, IrCl(CO)(PPh), when combined with KI as an additive, served as an excellent catalyst for the decarbonylation of long-chain aliphatic carboxylic acids to give internal alkenes with high selectivity. On combination with KI and AcO as additives under controlled temperatures, decarbonylation proceeded to give terminal alkenes with high selectivity. © 2011 American Chemical Society.
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