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Efficient iridium-catalyzed decarbonylation reaction of aliphatic carboxylic acids leading to internal or terminal alkenes

Organometallics, ISSN: 0276-7333, Vol: 30, Issue: 6, Page: 1389-1394
2011
  • 59
    Citations
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  • 61
    Captures
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Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    59
    • Citation Indexes
      59
  • Captures
    61

Article Description

Vaska's complex, IrCl(CO)(PPh), when combined with KI as an additive, served as an excellent catalyst for the decarbonylation of long-chain aliphatic carboxylic acids to give internal alkenes with high selectivity. On combination with KI and AcO as additives under controlled temperatures, decarbonylation proceeded to give terminal alkenes with high selectivity. © 2011 American Chemical Society.

Bibliographic Details

Maetani, Shinji; Fukuyama, Takahide; Suzuki, Nobuyoshi; Ishihara, Daisuke; Ryu, Ilhyong

American Chemical Society (ACS)

Chemistry

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