Synthesis, characterization, and catalytic activity of alcohol- functionalized NHC gold(I/III) complexes
Organometallics, ISSN: 1520-6041, Vol: 33, Issue: 9, Page: 2326-2335
2014
- 24Citations
- 44Captures
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Article Description
A series of alcohol-functionalized NHC gold(I/III) complexes of the types [(L)Au(Cl or NTf)] and [(L)AuCl] (L = IPrEtOH, (1, 4, 5), IMesEtOH (2, 6), IMeEtOH (3, 7)) was readily synthesized and characterized by NMR spectroscopy and single-crystal X-ray diffraction. The catalytic activity of the new complexes was assessed and compared with that of other gold catalysts, in the tandem 3,3-rearrangement-Nazarov reactions of enynyl acetate and the rearrangement reaction of alkynyloxirane. The new complexes appeared to be dual-site catalysts in both transformations, thanks to the presence of the primary alcohol function tethered to the NHC ligands. © 2014 American Chemical Society.
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