Porphyrin-naphthodiimide interactions as a structural motif in foldamers and supramolecular assemblies
Organic and Biomolecular Chemistry, ISSN: 1477-0520, Vol: 6, Issue: 14, Page: 2534-2543
2008
- 15Citations
- 12Captures
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Article Description
π-π Stacking interactions between electron deficient naphthalenediimides (NDI) and electron-rich porphyrins (POR) leading to charge transfer are shown to be prevalent in linked NDI-POR and POR-NDI-POR structures. For flexibly-linked systems, intramolecular interactions lead to S-shaped foldamers in solution, whereas intermolecular association is predominant in more rigid systems. The foldamer structures can be interrupted by competing aromatic solvents, by six-coordination of metallated porphyrin derivatives, by protonation of the free base porphyrin in non-metallated structures, and in facially sterically hindered porphyrins. © The Royal Society of Chemistry 2008.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=46749143792&origin=inward; http://dx.doi.org/10.1039/b804267e; http://www.ncbi.nlm.nih.gov/pubmed/18600275; https://xlink.rsc.org/?DOI=b804267e; https://dx.doi.org/10.1039/b804267e; https://pubs.rsc.org/en/content/articlelanding/2008/ob/b804267e
Royal Society of Chemistry (RSC)
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