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A series of novel 2D heterometallic 3d-4f heptanuclear complexes based on the linkages of Ln(ina) chains and [Cu(CN)] chains

CrystEngComm, ISSN: 1466-8033, Vol: 11, Issue: 9, Page: 2003-2008
2009
  • 37
    Citations
  • 0
    Usage
  • 6
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    37
    • Citation Indexes
      37
  • Captures
    6

Article Description

Five novel 2D heterometallic coordination polymers, LnCu (ina)(CN)·4HO [Ln = Nd (1), Eu (2), Tb (3), Gd (4), Sm (5); ina = isonicotinic acid], have been synthesized under hydrothermal conditions and characterized by elemental, infrared, thermogravimetric and X-ray diffraction analyses. These complexes are constructed of Ln(ina) chains, Cu-CN-Cu, and CN-Cu-CN chains, which represent the first examples of 3D coordination compounds created by using a combination of metal-cyanide chains, lanthanide-carboxylate linear chains and O-H⋯N hydrogen bonds. © 2009 The Royal Society of Chemistry.

Bibliographic Details

Zhao Yang Li; Ning Wang; Jing Wei Dai; Shan Tang Yue; Ying Liang Liu

Royal Society of Chemistry (RSC)

Chemistry; Materials Science; Physics and Astronomy

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