A series of novel 2D heterometallic 3d-4f heptanuclear complexes based on the linkages of Ln(ina) chains and [Cu(CN)] chains
CrystEngComm, ISSN: 1466-8033, Vol: 11, Issue: 9, Page: 2003-2008
2009
- 37Citations
- 6Captures
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Article Description
Five novel 2D heterometallic coordination polymers, LnCu (ina)(CN)·4HO [Ln = Nd (1), Eu (2), Tb (3), Gd (4), Sm (5); ina = isonicotinic acid], have been synthesized under hydrothermal conditions and characterized by elemental, infrared, thermogravimetric and X-ray diffraction analyses. These complexes are constructed of Ln(ina) chains, Cu-CN-Cu, and CN-Cu-CN chains, which represent the first examples of 3D coordination compounds created by using a combination of metal-cyanide chains, lanthanide-carboxylate linear chains and O-H⋯N hydrogen bonds. © 2009 The Royal Society of Chemistry.
Bibliographic Details
Royal Society of Chemistry (RSC)
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