Thermally induced crystal-to-crystal transformations accompanied by changes in the magnetic properties of a Cu-p-hydroquinonate polymer
CrystEngComm, ISSN: 1466-8033, Vol: 13, Issue: 2, Page: 391-395
2011
- 14Citations
- 7Captures
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Article Description
In the Cu-p-hydroquinonate coordination polymer 1, the major pathway for antiferromagnetic exchange coupling runs along the hydroquinonate linker. Upon heating, 1 looses its supporting DMF ligands in a two-step sequence; the antiferromagnetic Cu-Cu interaction in the final product 3 is now mediated by two bridging oxygen atoms which results in an increase of the J value by two orders of magnitude. © 2011 The Royal Society of Chemistry.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=78650402449&origin=inward; http://dx.doi.org/10.1039/c0ce00367k; http://xlink.rsc.org/?DOI=C0CE00367K; http://pubs.rsc.org/en/content/articlepdf/2011/CE/C0CE00367K; https://xlink.rsc.org/?DOI=C0CE00367K; https://dx.doi.org/10.1039/c0ce00367k; https://pubs.rsc.org/en/content/articlelanding/2011/ce/c0ce00367k
Royal Society of Chemistry (RSC)
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