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Thermally induced crystal-to-crystal transformations accompanied by changes in the magnetic properties of a Cu-p-hydroquinonate polymer

CrystEngComm, ISSN: 1466-8033, Vol: 13, Issue: 2, Page: 391-395
2011
  • 14
    Citations
  • 0
    Usage
  • 7
    Captures
  • 0
    Mentions
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Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    14
    • Citation Indexes
      14
  • Captures
    7

Article Description

In the Cu-p-hydroquinonate coordination polymer 1, the major pathway for antiferromagnetic exchange coupling runs along the hydroquinonate linker. Upon heating, 1 looses its supporting DMF ligands in a two-step sequence; the antiferromagnetic Cu-Cu interaction in the final product 3 is now mediated by two bridging oxygen atoms which results in an increase of the J value by two orders of magnitude. © 2011 The Royal Society of Chemistry.

Bibliographic Details

Ngoc Hien Phan; Edith Alig; Lothar Fink; Hans Wolfram Lerner; Matthias Wagner; Ivan Halasz; Robert Dinnebier; Ingo Opahle; Harald O. Jeschke; Roser Valentí; Jan W. Bats; Pham Thanh Cong; Bernd Wolf; Michael Lang; Biprajit Sarkar

Royal Society of Chemistry (RSC)

Chemistry; Materials Science; Physics and Astronomy

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