Conformational control of ligands to create a finite metal-organic cluster and an extended metal-organic framework
CrystEngComm, ISSN: 1466-8033, Vol: 15, Issue: 2, Page: 259-264
2013
- 29Citations
- 17Captures
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Article Description
While a twofold interpenetrated 3-D metal-organic framework, [Cu 3(L1)2(H2O)3] ·14DMF·16H2O (1) (where, L1 is 4,4′,4″-[1,3,5-benzenetriyltris(carbonylimino)]trisbenzoate and DMF is N,N′-dimethylformamide), with a (3,4)-connected pto net topology was prepared using a tricarboxylic acid linked via secondary benzamide as an extended 3-connected node and a Cu paddle-wheel secondary building unit as a planar 4-connected node, another tricarboxylic acid with methylated tertiary benzamide linkage in a folded geometry completely converted its role from diverging to chelating ligand and resulted in a finite Ni14 metal-organic cluster, [Ni14(μ3-OH)8(L 2)6(formate)2(DMF)10(H 2O)2]·28DMF·14H2O (2) (where L2 is N,N′,N″-methyl-4,4′,4″-[1,3,5- benzenetriyltris(carbonylimino)]trisbenzoate). © 2013 The Royal Society of Chemistry.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84870863507&origin=inward; http://dx.doi.org/10.1039/c2ce26015h; https://xlink.rsc.org/?DOI=C2CE26015H; http://xlink.rsc.org/?DOI=C2CE26015H; http://pubs.rsc.org/en/content/articlepdf/2013/CE/C2CE26015H; https://dx.doi.org/10.1039/c2ce26015h; https://pubs.rsc.org/en/content/articlelanding/2013/ce/c2ce26015h
Royal Society of Chemistry (RSC)
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