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Conformational control of ligands to create a finite metal-organic cluster and an extended metal-organic framework

CrystEngComm, ISSN: 1466-8033, Vol: 15, Issue: 2, Page: 259-264
2013
  • 29
    Citations
  • 0
    Usage
  • 17
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    29
    • Citation Indexes
      29
  • Captures
    17

Article Description

While a twofold interpenetrated 3-D metal-organic framework, [Cu 3(L1)2(H2O)3] ·14DMF·16H2O (1) (where, L1 is 4,4′,4″-[1,3,5-benzenetriyltris(carbonylimino)]trisbenzoate and DMF is N,N′-dimethylformamide), with a (3,4)-connected pto net topology was prepared using a tricarboxylic acid linked via secondary benzamide as an extended 3-connected node and a Cu paddle-wheel secondary building unit as a planar 4-connected node, another tricarboxylic acid with methylated tertiary benzamide linkage in a folded geometry completely converted its role from diverging to chelating ligand and resulted in a finite Ni14 metal-organic cluster, [Ni14(μ3-OH)8(L 2)6(formate)2(DMF)10(H 2O)2]·28DMF·14H2O (2) (where L2 is N,N′,N″-methyl-4,4′,4″-[1,3,5- benzenetriyltris(carbonylimino)]trisbenzoate). © 2013 The Royal Society of Chemistry.

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