Ni(ii)/BINOL-catalyzed alkenylation of unactivated C(sp)-H bonds
Chemical Communications, ISSN: 1364-548X, Vol: 51, Issue: 37, Page: 7899-7902
2015
- 79Citations
- 33Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations79
- Citation Indexes79
- 79
- CrossRef75
- Captures33
- Readers33
- 33
Article Description
The first nickel-catalyzed alkenylation of unactivated C(sp)-H bonds with vinyl iodides is described. The catalytic system comprises an inexpensive and air-stable Ni(acac) as the catalyst and BINOL as the ligand, which is highly efficient for the alkenylation of β-methyl C(sp)-H bonds of a broad range of aliphatic carboxamides. The resulting olefins can serve as versatile handles for further preparation. Additionally, we also demonstrated the synthesis of functionalized carboxamides bearing α-quaternary carbon centers from simple pivalamide via nickel-catalyzed sequential C(sp)-H bond functionalization.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84928532997&origin=inward; http://dx.doi.org/10.1039/c5cc02254a; http://www.ncbi.nlm.nih.gov/pubmed/25857332; https://xlink.rsc.org/?DOI=C5CC02254A; http://xlink.rsc.org/?DOI=C5CC02254A; http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC02254A; https://dx.doi.org/10.1039/c5cc02254a; https://pubs.rsc.org/en/content/articlelanding/2015/cc/c5cc02254a
Royal Society of Chemistry (RSC)
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