Titanium carbenoid-mediated cyclopropanation of allylic alcohols: Selectivity and mechanism
Organic and Biomolecular Chemistry, ISSN: 1477-0520, Vol: 13, Issue: 22, Page: 6325-6332
2015
- 11Citations
- 18Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations11
- Citation Indexes11
- 11
- CrossRef10
- Captures18
- Readers18
- 18
Article Description
A new method for the chemo- and stereoselective conversion of allylic alcohols into the corresponding cyclopropane derivatives has been developed. The cyclopropanation reaction was carried out with an unprecedented titanium carbenoid generated in situ from Nugent's reagent, manganese and methylene diiodide. The reaction involving the participation of an allylic hydroxyl group, proceeded with conservation of the alkene geometry and in a high diastereomeric excess. The scope, limitations and mechanism of this metal-catalysed reaction are discussed. This journal is
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84930660729&origin=inward; http://dx.doi.org/10.1039/c5ob00544b; http://www.ncbi.nlm.nih.gov/pubmed/25968250; https://xlink.rsc.org/?DOI=C5OB00544B; http://xlink.rsc.org/?DOI=C5OB00544B; http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB00544B; https://dx.doi.org/10.1039/c5ob00544b; https://pubs.rsc.org/en/content/articlelanding/2015/ob/c5ob00544b
Royal Society of Chemistry (RSC)
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