Early stages of catalyst aging in the iridium mediated water oxidation reaction
Physical Chemistry Chemical Physics, ISSN: 1463-9076, Vol: 18, Issue: 16, Page: 10931-10940
2016
- 14Citations
- 32Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations14
- Citation Indexes14
- CrossRef14
- 13
- Captures32
- Readers32
- 32
Article Description
When exposed to a potential exceeding 1.5 V versus RHE for several minutes the molecular iridium bishydroxide complex bearing a pentamethylcyclopentadienyl and a N-dimethylimidazolin-2-ylidene ligand spontaneously adsorbs onto the surface of glassy carbon and gold electrodes. Simultaneously with the adsorption of the material on the electrode, the evolution of dioxygen is detected and modifications of the catalyst structure are observed. XPS and XAS studies reveal that the species present at the electrode interface is best described as a partly oxidized molecular species rather than the formation of large aggregates of iridium oxide. These findings are in line with the unique kinetic profile of the parent complex in the water oxidation reaction.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84966373186&origin=inward; http://dx.doi.org/10.1039/c6cp00751a; http://www.ncbi.nlm.nih.gov/pubmed/27040354; http://xlink.rsc.org/?DOI=C6CP00751A; http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP00751A; https://xlink.rsc.org/?DOI=C6CP00751A; https://dx.doi.org/10.1039/c6cp00751a; https://pubs.rsc.org/en/content/articlelanding/2016/cp/c6cp00751a
Royal Society of Chemistry (RSC)
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