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Synthesis and characterization of novel dibenz[: A, c] anthracenedicarboxythioimides: The effect of thionation on self-assembly

RSC Advances, ISSN: 2046-2069, Vol: 6, Issue: 82, Page: 78784-78790
2016
  • 6
    Citations
  • 0
    Usage
  • 11
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    6
    • Citation Indexes
      6
  • Captures
    11

Article Description

We report the synthesis and properties of a series of novel dibenzanthracenedicarboxythioimides and an investigation of the effects of thionation on self-assembly in these systems. These compounds all display columnar mesophases over broad temperature ranges and self-associate to form dimers in solution. Overall, thionation slightly improves self-assembly in these systems. Furthermore, increasing the thionation of these materials leads to a lowering of the LUMO energy and a narrowing of the HOMO-LUMO band gap.

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