One-pot redox synthesis of Pt/FeO catalyst for efficiently chemoselective hydrogenation of cinnamaldehyde
RSC Advances, ISSN: 2046-2069, Vol: 7, Issue: 34, Page: 21107-21113
2017
- 18Citations
- 24Captures
Metric Options: CountsSelecting the 1-year or 3-year option will change the metrics count to percentiles, illustrating how an article or review compares to other articles or reviews within the selected time period in the same journal. Selecting the 1-year option compares the metrics against other articles/reviews that were also published in the same calendar year. Selecting the 3-year option compares the metrics against other articles/reviews that were also published in the same calendar year plus the two years prior.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Article Description
External additives (i.e., ionic electride donors) are usually necessary to obtain a high catalytic performance in an electron-density-dependent chemoselective hydrogenation reaction. Here, a sphere-shaped Pt/FeO catalyst is prepared through a one-pot redox reaction using Pt(iv) and Fe(ii) precursors. The experimental results show that the prepared Pt/FeO catalyst with an Fe to Pt mole ratio of 100 : 1 can afford a high conversion of 94.2% towards cinnamaldehyde (CAL) and good selectivity of 92.2% towards cinnamyl alcohol (COL) under the mild conditions of 303 K, 5 bar H for 150 min in the chemoselective reduction of CAL. The excellent catalytic performance could be attributed to the dissociation of H and adsorption of CAL via a vertical configuration modulated by the electronic effect between Pt and FeO, and the abundant available active sites induced by uniformly dispersed Pt nanoparticles. Additionally, the intrinsic magnetism of FeO nanospheres endows the catalyst with a rapid separation property, favourable for repeated use of a catalyst.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85017725927&origin=inward; http://dx.doi.org/10.1039/c7ra02898a; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85018498583&origin=inward; http://xlink.rsc.org/?DOI=C7RA02898A; http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA02898A; https://xlink.rsc.org/?DOI=C7RA02898A; https://dx.doi.org/10.1039/c7ra02898a; https://pubs.rsc.org/en/content/articlelanding/2017/ra/c7ra02898a
Royal Society of Chemistry (RSC)
Provide Feedback
Have ideas for a new metric? Would you like to see something else here?Let us know