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An unprecedented {NiSiW} hybrid polyoxometalate with high photocatalytic hydrogen evolution activity

Chemical Communications, ISSN: 1364-548X, Vol: 55, Issue: 29, Page: 4166-4169
2019
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Article Description

A unique polyoxometalate complex made up of a tetradecanuclear nickel bisphosphonate cluster capping a {SiW} unit has been characterized. This stable compound exhibits a high hydrogen evolution reaction photocatalytic activity under visible light irradiation via a reductive quenching mechanism.

Bibliographic Details

Paille, Grégoire; Boulmier, Amandine; Bensaid, Alexandre; Ha-Thi, Minh-Huong; Tran, Thu-Trang; Pino, Thomas; Marrot, Jérôme; Rivière, Eric; Hendon, Christopher H; Oms, Olivier; Gomez-Mingot, Maria; Fontecave, Marc; Mellot-Draznieks, Caroline; Dolbecq, Anne; Mialane, Pierre

Royal Society of Chemistry (RSC)

Chemical Engineering; Materials Science; Chemistry

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