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Is basicity the sole criterion for attaining high carbon dioxide capture in deep-eutectic solvents?

Physical Chemistry Chemical Physics, ISSN: 1463-9076, Vol: 22, Issue: 3, Page: 966-970
2020
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Article Description

A critical analysis of the role of Hammett basicity (H) and aqueous basicity (pK) in CO uptake in deep-eutectic solvents (DESs) suggests that neither H nor pK correlates with the CO w/w% capacity in the studied DESs. Instead, strong "synergistic interactions" between donor and acceptor moieties satisfactorily relate to the w/w% of CO in DESs.

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