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High temperature lead-free BNT-based ceramics with stable energy storage and dielectric properties

Journal of Materials Chemistry A, ISSN: 2050-7496, Vol: 8, Issue: 2, Page: 683-692
2020
  • 188
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  • 33
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Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    188
    • Citation Indexes
      188
  • Captures
    33

Article Description

High-temperature dielectric ceramics are in urgent demand due to the rapid development of numerous emerging applications. However, producing dielectric ceramics with favorable temperature, frequency and electric field stability is still a huge challenge. The construction of multi-phase coexistence material systems is an effective way to obtain stable dielectric and energy storage properties. In this work, NaNbO (NN) modified 0.95BiNaTiO-0.05SrZrO (BNTSZ) ceramics ((1 - x)BNTSZ-xNN) are designed to achieve the coexistence of rhombohedral and tetragonal phases. The variation in the dielectric permittivity of the 0.8BNTSZ-0.2NN ceramic is less than ±15% over the temperature range from -55 °C to 545 °C, which is the reported record-high upper operating temperature, with a high room-temperature dielectric permittivity of 1170. The 0.8BNTSZ-0.2NN ceramic exhibits excellent frequency and electric field stability as well. Additionally, a large discharge energy density of 3.14 J cm is obtained in the 0.85BNTSZ-0.15NN ceramic with an energy efficiency of 79% at a high temperature of 120 °C under 230 kV cm, with the variation in the discharge energy density being less than ±4% in the temperature range from 25 °C to 180 °C under 120 kV cm. All these features demonstrate that the (1 - x)BNTSZ-xNN ceramics are promising candidates for use at extremely high temperature in both dielectric and energy storage capacitor applications.

Bibliographic Details

Chaoqiong Zhu; Ziming Cai; Bingcheng Luo; Longtu Li; Xiaohui Wang; Limin Guo

Royal Society of Chemistry (RSC)

Chemistry; Energy; Materials Science

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