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Efficient synthesis and unit-selective π-extension of π-fused [4.3.3]propellane as a chiral building block

Chemical Communications, ISSN: 1364-548X, Vol: 59, Issue: 46, Page: 7080-7083
2023
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Article Description

A three-dimensional skeleton, π-fused [4.3.3]propellane, was constructed and derivatized by selective π-extension at the two naphthalene units. The obtained propellanes existed as stereoisomers different in spatial arrangement, one of which displayed a chiroptical response originating from through-space interactions between 5-azachrysenes in a skew position.

Bibliographic Details

Kato, Kenichi; Tanaka, Seigo; Seto, Nobuyoshi; Wada, Keisuke; Gon, Masayuki; Fa, Shixin; Ohtani, Shunsuke; Tanaka, Kazuo; Ogoshi, Tomoki

Royal Society of Chemistry (RSC)

Materials Science; Chemical Engineering; Chemistry

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