Approach to the tricritical point in bimodal polymer solutions
The Journal of Chemical Physics, ISSN: 0021-9606, Vol: 91, Issue: 3, Page: 1897-1903
1989
- 17Citations
- 2Captures
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Article Description
The approach to the tricritical point in bimodal polymer solutions is analyzed in the (meanfield) Flory-Huggins approximation. The parameter governing the thermodynamic properties of the system is the ratio of the molecular weights of the two polymer homologues. When this ratio exceeds a certain value r, a separation in three phases is possible. The different dimensions of the three phase region vary with r as simple characteristic powers of the distance to this tricritical ratio (r-r). Comparison with experiments reveals some shortcomings of the Flory-Huggins approximation. © 1989 American Institute of Physics.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0009077003&origin=inward; http://dx.doi.org/10.1063/1.457095; https://pubs.aip.org/jcp/article/91/3/1897/220892/Approach-to-the-tricritical-point-in-bimodal; http://aip.scitation.org/doi/10.1063/1.457095; https://aip.scitation.org/action/captchaChallenge?redirectUrl=https%3A%2F%2Faip.scitation.org%2Fdoi%2F10.1063%2F1.457095
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