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Vector parametrization of the N-atom problem in quantum mechanics. II. Coupled-angular-momentum spectral representations for four-atom systems

Journal of Chemical Physics, ISSN: 0021-9606, Vol: 108, Issue: 21, Page: 8821-8829
1998
  • 70
    Citations
  • 0
    Usage
  • 25
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    70
    • Citation Indexes
      70
  • Captures
    25

Article Description

Within the framework of adapted coupled-angular-momentum spectral representations, the geometrical description of a four-atom molecular system by three Jacobi relative position vectors is shown to result in matrices representing the kinetic energy operator, prediagonalized to a very large extent. A fully diagonal representation is built for the angular (internal and rotational) part of the problem. © 1998 American Institute of Physics.

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