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Magnetic moments and coordination symmetry in bcc Fe-M alloys

Physical Review B, ISSN: 0163-1829, Vol: 31, Issue: 4, Page: 2521-2523
1985
  • 28
    Citations
  • 0
    Usage
  • 5
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    28
    • Citation Indexes
      28
  • Captures
    5

Article Description

A directed valence analysis of metalloid (M) atoms in various structures has been performed and discussed in terms of the ligand p-d bond model. It is shown that p-d bonding cannot have a direct effect on the moment of Fe atoms in bcc Fe-M alloys, whereas in most other transition-metal metalloid (T-M) structures with ferromagnetic T atoms as solvents, it is shown that p-d bonding can reduce the moments of the T atoms. The small moment variations in bcc Fe-M alloys could be caused instead by variations in the intraband exchange splitting, as a result of changes in the lattice constant. © 1985 The American Physical Society.

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