(1R,2R)-N,N′-Diisobutyl-N,N′-dimethyl-cyclo-hexane-1,2-diamine
Acta Crystallographica Section E: Structure Reports Online, ISSN: 1600-5368, Vol: 65, Issue: 5, Page: o956
2009
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Article Description
The title compound, CH3N, is a chiral diamine with fixed R configuration at both stereogenic carbon centres of the cyclo-hexane backbone. Due to their different substituents, the two N atoms also become stereogenic. In the crystal structure, the configuration at one of the two nitro-gen centres is fixed, with the free electron pair pointing inward and the isobutyl group in a trans position towards the cyclo-hexane backbone resulting in an R configuration. The isobutyl group at the second N atom, however, is disordered with 75% S configuration and 25% R configuration. In both cases, the isobutyl group is arranged in a trans position towards the cyclo-hexane backbone.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=66749183481&origin=inward; http://dx.doi.org/10.1107/s160053680901109x; http://www.ncbi.nlm.nih.gov/pubmed/21583999; https://journals.iucr.org/paper?S160053680901109X; http://scripts.iucr.org/cgi-bin/paper?S160053680901109X; http://journals.iucr.org/e/issues/2009/05/00/fi2074/fi2074.pdf; https://dx.doi.org/10.1107/s160053680901109x; https://journals.iucr.org/e/issues/2009/05/00/fi2074/index.html
International Union of Crystallography (IUCr)
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