(2.2.2-Cryptand)potassium tetra-carbonyl-cobaltate(-I).

Citation data:

Acta crystallographica. Section E, Structure reports online, ISSN: 1600-5368, Vol: 70, Issue: Pt 5, Page: m180

Publication Year:
2014
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PMID:
24860312
DOI:
10.1107/s1600536814006758, 10.1107/s1600536814006758/nk2222isup2.hkl, 10.1107/s1600536814006758/nk2222sup0.html, 10.1107/s1600536814006758/nk2222sup1.cif
PMCID:
PMC4011216
Author(s):
Brennessel, William W, Ellis, John E
Publisher(s):
International Union of Crystallography (IUCr), International Union of Crystallography
Tags:
Physics and Astronomy, Materials Science, Chemistry
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article description
The title salt, [K(C18H36N2O6)][Co(CO)4], is an example of a classical carbonyl-metalate. The asymmetric unit contains one cation and one tetrahedral anion, both in general positions. Based on comparison of the four carbonyl C-O bond lengths and C-Co-C angles, the anion is unperturbed by the cation, which is normal for an alkali metal fully encased by a cryptand cage.

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