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The thermodynamic parameters of formation of ions in the interaction of alkylaluminum with electron donors

Russian Journal of Physical Chemistry A, ISSN: 0036-0244, Vol: 80, Issue: 8, Page: 1181-1190
2006
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Article Description

The thermodynamic parameters of formation of ions in the system AlMe + electron donor (D) in the presence and absence of water microimpurities were determined. The structure of these ions was studied and their concentration in nonpolar media was estimated for the example of D = pyridine. The conclusion was drawn from the results of calculations that the participation of water resulted in a substantial increase in the concentration of ions. © Nauka/Interperiodica 2006.

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