Features of Cl K-edge XANES Spectra of Transition Metal Complexes {MCl} (M = Rh, Pd, Re, Os, Ir, Pt)
Bulletin of the Russian Academy of Sciences: Physics, ISSN: 1934-9432, Vol: 87, Issue: 5, Page: 654-661
2023
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Article Description
Abstract: Cl K-edges of a wide range of chlorides of 4d and 5d transition metals {MCl} (M = Rh, Pd, Re, Os, Ir, Pt) are obtained using the Kosmos station of the VEPP-4 synchrotron. The combined use of experimental X-ray and theoretical means allows determination of the magnitude of spin–orbit coupling (SOC), depending on the transition metal. The features of the Cl K-edge are analyzed with and without SOC, and upon stretching and compression of the complexes.
Bibliographic Details
Allerton Press
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