Palladium and Platinum 2,4--amino Azetidine and Related Complexes.

Citation data:

Frontiers in chemistry, ISSN: 2296-2646, Vol: 6, Issue: JUN, Page: 211

Publication Year:
2018
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PMID:
29977888
DOI:
10.3389/fchem.2018.00211; 10.3389/fchem.2018.00211.s002; 10.3389/fchem.2018.00211.s001; 10.3389/fchem.2018.00211.s003
Author(s):
Yoshizawa, Akina; Feula, Antonio; Leach, Andrew G.; Male, Louise; Fossey, John S.
Publisher(s):
Frontiers Media SA
Tags:
Chemistry
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article description
Seven '-palladium(II) chloride complexes, one '-palladium(II) acetate complex of 2,4--azetidines where prepared and analyzed by single crystal XRD. Two platinum(II) chloride '-complexes of 2,4--azetidines where prepared and analyzed by single crystal XRD. Computational analysis and determination of the %Vbur was examined conducted. A ' metallocyclic complex was prepared by oxidative addition of palladium(0) to an ortho bromo 2,4--disubstituted azetidine and its crystal structure displays a slightly pyramidalized metal-ligand orientation.