Bifunctional catalysts of Co3O4@GCN tubular nanostructured (TNS) hybrids for oxygen and hydrogen evolution reactions

Citation data:

Nano Research, ISSN: 1998-0124, Vol: 8, Issue: 11, Page: 3725-3736

Publication Year:
2015
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Citations 43
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Repository URL:
https://ro.uow.edu.au/aiimpapers/1802; http://ro.uow.edu.au/aiimpapers/1695
DOI:
10.1007/s12274-015-0872-1
Author(s):
Tahir, Muhammad Nawaz; Mahmood, Nasir; Zhang, Xiaoxue; Mahmood, Tariq; Butt, Faheem K; Aslam, Imran; Tanveer, M; Idrees, Faryal; Khalid, Syed; Shakir, Imran; Yan, Yiming; Zou, Jijun; Cao, Chuanbao; Hou, Yanglong Show More Hide
Publisher(s):
Springer Nature
Tags:
Materials Science; Engineering; tns; nanostructured; tubular; gcn; reactions; 4; evolution; o; 3; co; catalysts; bifunctional; hydrogen; oxygen; hybrids; co3o4; Physical Sciences and Mathematics
article description
Catalysts for oxygen and hydrogen evolution reactions (OER/HER) are at the heart of renewable green energy sources such as water splitting. Although incredible efforts have been made to develop efficient catalysts for OER and HER, great challenges still remain in the development of bifunctional catalysts. Here, we report a novel hybrid of CoOembedded in tubular nanostructures of graphitic carbon nitride (GCN) and synthesized through a facile, large-scale chemical method at low temperature. Strong synergistic effects between CoOand GCN resulted in excellent performance as a bifunctional catalyst for OER and HER. The high surface area, unique tubular nanostructure, and composition of the hybrid made all redox sites easily available for catalysis and provided faster ionic and electronic conduction. The CoO@GCN tubular nanostructured (TNS) hybrid exhibited the lowest overpotential (0.12 V) and excellent current density (147 mA/cm) in OER, better than benchmarks IrOand RuO, and with superior durability in alkaline media. Furthermore, the CoO@GCN TNS hybrid demonstrated excellent performance in HER, with a much lower onset and overpotential, and a stable current density. It is expected that the CoO@GCN TNS hybrid developed in this study will be an attractive alternative to noble metals catalysts in large scale water splitting and fuel cells. [Figure not available: see fulltext.]