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Saudiarabicains A-E, bioactive 19-acetoxyingol diterpenoids from Euphorbia saudiarabica

Tetrahedron Letters, ISSN: 0040-4039, Vol: 61, Issue: 32, Page: 152203
2020
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Article Description

Five new 19-acetoxyingols were isolated from the aerial parts of Euphorbia saudiarabica. They included two uncommon pentacyclic acetoxyingols ( 1, 2 ) and two 2,3-diepimers ( 3, 4 ), representing the first report of 19-acetoxyingols epimers. Their structures were determined by analysis of extensive 1D and 2D NMR spectroscopic data. The absolute configurations were established by experimental and calculated CD analysis. Compounds 3 – 5 showed α-glucosidase inhibitory effects superior to the positive control, acarbose (IC 50 9.1, 8.0, 1.8 vs 147 µM, respectively). Compounds 1, 2, 4, and 5 showed inhibitory effects on human P-glycoprotein comparable to the positive control, valspodar (IC 50 0.1–1.4 vs 0.2 µM, respectively).

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