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Thermodynamic Properties of the System PuCl3-KCl

1958
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Thesis / Dissertation Description

This paper is a dissertation on a study of the determination of the Gibbs free energy of formation of plutonium chloride using potentiometric measurements obtained from a galvanic cell of the type,Ta, Pu(1)/ PuCl3-KCl(1,N1)/ Cl2(g), C.The terminals of the two electrodes, tantalum and graphite, have been included in the representation inasmuch as their effects must be taken into consideration in the design of the cell; however, in order that the desired virtual cell reaction be realized, it is necessary that these terminals be chemically inert.

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