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A Thermodynamic and Defect Study of Nonstoichiometric Calcium Doped Cerium Dioxide

1998
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Thesis / Dissertation Description

The aim of this investigation is to study the defect reactions and the associated thermodynamic behavior of calcium doped cerium dioxide as a function of nonstoichiometry. These defect reactions, involve the formation of oxygen vacancies, electrons, and holes which determine the nonstoichiometry, x, of the material as a function of temperature and oxygen partial pressure, Po2...

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