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The Effect of Peripheral Circuits on the Total \pi-Electron Energies of Cyclacenes

Vol: 24, Issue: 3, Page: 217-222
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Article Description

Within the framework of the Hückel molecular orbital theory, certain linear models are developed to express the contribution of peripheral circuits of cyclacenes into their total \pi-electron energies, which explain why cyclacenes exhibit the cryptoannulenic behavior as their peripheral circuits which are annulenic in character.

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