Tris(ethylenediamine)cobalt(III) nonaiododibismuthate
Acta Crystallographica Section E: Structure Reports Online, ISSN: 1600-5368, Vol: 61, Issue: 8, Page: m1531-m1533
2005
- 10Citations
- 597Usage
- 5Captures
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Metrics Details
- Citations10
- Citation Indexes10
- 10
- CrossRef8
- Usage597
- Downloads530
- Abstract Views67
- Captures5
- Readers5
Article Description
The asymmetric unit of the title compound, [Co(CH N)][BiI], crystallizes in the orthorhombic space group Cmc2. The asymmetric unit contains half of a [Co(en)] cation (en is ethylenediamine) and half of a [BiI] anion. Both species are located on mirror planes, requiring the [Co(en) ] cation to be present as a statistically disordered mixture of both enantiomeric forms. Crystals were grown solvothermally from an ethanol-water solvent mixture using rac-[Co(en)]I and bismuth triiodide as starting materials. The compound is a rare example of a mixed-metal halobismuthate material. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
Bibliographic Details
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=32244442174&origin=inward; http://dx.doi.org/10.1107/s1600536805021501; https://journals.iucr.org/paper?S1600536805021501; http://scripts.iucr.org/cgi-bin/paper?S1600536805021501; http://journals.iucr.org/e/issues/2005/08/00/sj6094/sj6094.pdf; https://scholarcommons.sc.edu/chem_facpub/61; https://scholarcommons.sc.edu/cgi/viewcontent.cgi?article=1058&context=chem_facpub; https://dx.doi.org/10.1107/s1600536805021501
International Union of Crystallography (IUCr)
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