Low temperature magnetic properties of the bimetallic compounds [Co(C 5 H 5 NO) 6 ](MX 4 ) (M = Co 2+ , Zn 2+ ; X = Cl - , Br - )
Journal of Magnetism and Magnetic Materials, ISSN: 0304-8853, Vol: 44, Issue: 1, Page: 77-88
1984
- 9Citations
- 2Usage
- 2Captures
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Metrics Details
- Citations9
- Citation Indexes9
- CrossRef8
- Usage2
- Abstract Views2
- Captures2
- Readers2
Article Description
We have measured the specific heat and suceptibility of the compounds [Co(C 5 H 5 NO) 6 ] (MX 4 ) (M = Co, Zn; X = Cl, Br), which are all isostructural and monoclinic. The data show that two magnetic subsystems are present in the Co/Co compounds. The Co 2+ ions on the octahedral positions of the chlorine compounds exhibit antiferromagnetic ordering at T c = 0.95(1) K, the Co 2+ ions on the tetrahedral positions remaining paramagnetic down to at least 0.04 K. The paramagnetic ions appear to experience two different molecular fields from the ordered Co 2+ ions. The behaviour of the bromine compounds is similar, the ordering temperature being about 0.65 K. Both chlorine compounds are apparently canted antiferromagnets. The bromine compounds show compensated antiferromagnetism.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/0304885384900489; http://dx.doi.org/10.1016/0304-8853(84)90048-9; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0021491058&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/0304885384900489; https://api.elsevier.com/content/article/PII:0304885384900489?httpAccept=text/xml; https://api.elsevier.com/content/article/PII:0304885384900489?httpAccept=text/plain; http://scholarsmine.mst.edu/chem_facwork/1699; http://scholarsmine.mst.edu/cgi/viewcontent.cgi?article=2698&context=chem_facwork; http://dx.doi.org/10.1016/0304-8853%2884%2990048-9; https://dx.doi.org/10.1016/0304-8853%2884%2990048-9
Elsevier BV
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