Selectivities in biomimetic atom abstraction reactions

Citation data:

Tetrahedron Letters, ISSN: 0040-4039, Vol: 32, Issue: 31, Page: 3759-3762

Publication Year:
1991
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Citations 21
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Repository URL:
https://aquila.usm.edu/fac_pubs/7045
DOI:
10.1016/s0040-4039(00)79369-5
Author(s):
Khanna, Rajive K.; Pauling, Teresa M.; Vajpayee, Dipti
Publisher(s):
Elsevier BV
Tags:
Biochemistry, Genetics and Molecular Biology; Chemistry; Pharmacology, Toxicology and Pharmaceutics; biomimetic; hydroxylation; oxometalloporphyrins; selectivities; atom abstraction; Physical Sciences and Mathematics
article description
Selectivities of oxometalloporphyrin complexes towards hydrogen atom abstraction from substituted toluenes decrease in the order CrO > FeO > MnO, which is in accord with the force constants of the MO bonds in these model oxygenases.