Copper-Catalyzed Arylation of 1H-Perfluoroalkanes

Citation data:

Journal of the American Chemical Society

Publication Year:
2011
Usage 28
Abstract Views 15
Downloads 13
Repository URL:
https://epublications.marquette.edu/chem_fac/389; https://epublications.marquette.edu/cgi/viewcontent.cgi?article=1389&context=chem_fac
Author(s):
Popov, Ilya; Lindeman, Sergey V.; Daugulis, Olafs
Publisher(s):
American Chemical Society; e-Publications@Marquette
Tags:
Chemistry
article description
A general method has been developed for arylation of readily available 1H-perfluoroalkanes. The method employs aryl iodide and 1H-perfluoroalkane reagents, DMPU solvent, TMP2Zn base, and a copper chloride/phenanthroline catalyst. Preliminary mechanistic studies are reported.