X-ray Structure of mer-[Mo(CO)3(PPh3)(κ 2-dppm)]

Citation data:

Journal of Chemical Crystallography, ISSN: 1074-1542, Vol: 40, Issue: 8, Page: 712-715

Publication Year:
2010
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Repository URL:
https://epublications.marquette.edu/chem_fac/549
DOI:
10.1007/s10870-010-9777-8
Author(s):
Ghosh, Shishir; Kabir, Shariff E.; Camellia, Faranza K.; Hossain, Md. Kamal; Haworth, Daniel T.; Lindeman, Sergey V.; Siddiquee, Tasneem A.; Bennett, Dennis W.
Publisher(s):
Springer Nature; Springer; e-Publications@Marquette
Tags:
Chemistry; Physics and Astronomy; Molybdenum; Bis(diphenylphosphino)methane; Triphenylphosphine; X-ray structure
article description
Treatment of [Mo(CO)(NCMe)] with bis (diphenylphosphino)methane (dppm) and triphenylphosphine (PPh) at 50 °C afforded mer-[Mo(CO)(PPh) (κ- dppm)] (1) in 55% yield which has been characterized by single crystal X-ray diffraction studies and spectroscopic measurements. Compound 1 crystallizes in the triclinic space group P-1 with a = 10.3449(6), b = 11.1570(6), c = 17.8961(10) Å , b = 80.8400(10)°, Z = 2 and V = 1959.8(2) Å 3. © Springer Science+Business Media, LLC 2010.