The reported anomalous emission intensity of the 5 D 0 → 7 F 4 transition of Eu 3+ in a molybdate double perovskite
- Citation data:
Journal of Materials Chemistry C, ISSN: 2050-7526, Vol: 3, Issue: 5, Page: 960-963
- Publication Year:
- Repository URL:
- https://repository.hkbu.edu.hk/hkbu_staff_publication/2550; https://repository.eduhk.hk/en/publications/7b00cff6-a2e0-4f7d-8e4b-1e0abc3bbc66
- Chemistry; Materials Science
The assigned anomalous upconversion emission intensity of theD→Ftransition of Euin the double perovskite SrCa(WMo)Oco-doped with Ybis shown to be due to a transition metal impurity present in the MoOstarting material. Relevant literature shows that the highest energyD→Ftransition is at a longer wavelength than 685 nm in molybdates. Cases of anomalous intensity of this transition are reviewed. Our 360 nm excited emission spectra of SrCa-EuYbLiMoOshow a very weakD→Ftransition, but on co-doping with Mn a structured band between 640 and 710 nm is observed due to Mn.