Tetra-ethyl-ammonium tri-μ-phenolato-bis-[tricarbonyl-manganate(I)].

Citation data:

Acta crystallographica. Section E, Structure reports online, ISSN: 1600-5368, Vol: 67, Issue: Pt 8, Page: m1150

Publication Year:
2011
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Repository URL:
https://scholarworks.wm.edu/chemistrypub/12
PMID:
22090909
DOI:
10.1107/s1600536811029266; 10.1107/s1600536811029266/bg2415sup0.html
PMCID:
PMC3212252
Author(s):
McNeese, Timothy J; Pike, Robert D
Publisher(s):
International Union of Crystallography (IUCr); International Union of Crystallography
Tags:
Chemistry; Materials Science; Physics and Astronomy
article description
The title compound, (C(8)H(20)N)[Mn(2)(C(6)H(5)O)(3)(CO)(6)], was synthesized from [Mn(CO)(3)(CH(3)CN)(3)]BF(4) and (C(8)H(20)N)(OC(6)H(5)). The binuclear anion exhibits a pseudo-threefold symmetry and contains two six-coordinate Mn atoms. Each metal atom is coordinated by three facially oriented CO ligands and three doubly-bridging phenolate ligands. The average O-Mn-O bond angle is 74.9 (7)° in the Mn(2)O(3) metal-phenolate dimeric core, yielding a distorted octa-hedron for each metal.