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Redox properties of CU(I) camphor hydrazone complexes

Portugaliae Electrochimica Acta, ISSN: 0872-1904, Vol: 29, Issue: 5, Page: 329-333
2011
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Article Description

The electrochemical properties of the one-dimensional coordination polymers [{CuX} (YNC H O)] (X=Cl: Y=NMe 1a, Y=NHMe 1b, Y=NH 1c; X=Br: Y=NH 2c) and dimers [{Cu(YNC H O)} (μ-X) ] (X=Cl: Y=NMe 3a; Y=NHMe 3b; X=Br: Y=NMe 4a; Y=NHMe 4b) were studied by cyclic voltammetry (CV) and controlled potential electrolysis (CPE). All complexes display anodic and cathodic processes. The anodic processes involve the oxidation of the metal site (Cu(I)→Cu(II)), while the cathodic processes are based on the ligand. The substituent (Y) at the camphor hydrazones (YNC H O) plays a relevant role in the electrochemical properties and reactivity of Cu(I) coordination polymers and Cu(I) dimmers, as corroborated by CPE.

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