Excess molar enthalpies for binary mixtures of different amines with water

Citation data:

The Journal of Chemical Thermodynamics, ISSN: 0021-9614, Vol: 89, Page: 16-21

Publication Year:
2015
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DOI:
10.1016/j.jct.2015.04.030
Author(s):
Ruilei Zhang, Jian Chen, Jianguo Mi
Publisher(s):
Elsevier BV
Tags:
Chemistry, Physics and Astronomy, Materials Science
article description
The isothermal excess molar enthalpies for binary mixtures of different amines with water were measured with a C-80 Setaram calorimeter. The experimental results indicate that the excess molar enthalpy is related to the molecular structure. The experimental excess molar enthalpies were satisfactorily fitted with the Redlich-Kister equation. They were also used to test the suitability of the NRTL model, and the deviations are a little larger than the R-K equation.

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