Reply to “Comments on ‘Analysis of the Nonrandom Two-Liquid Model for Prediction of Liquid–Liquid Equilibria’”

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Journal of Chemical & Engineering Data, ISSN: 0021-9568, Vol: 60, Issue: 5, Page: 1530-1531

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Zheng Li; Kathryn A. Mumford; Kathryn H. Smith; Jian Chen; Yong Wang; Geoffrey W. Stevens
American Chemical Society (ACS)
Chemistry; Chemical Engineering
article description
Researchers present their views on the comments on analysis of the nonrandom two-liquid model for prediction of liquid-liquid equilibria. The comments are provided by Marcilla and other researchers in a paper entitled ?Analysis of the Nonrandom Two-Liquid Model for Prediction of Liquid-Liquid Equilibria?. These researchers have claimed in their comments that the analysis presented in the paper seems to be not sufficiently precise or complete. Researchers reply to the comments state that minimization of Gibbs free energy is the necessary and sufficient condition for phase equilibrium, but the global minimum is difficult to obtain and can be time-consuming and tedious.