Anchoring effect of Ni 2+ in stabilizing reduced metallic particles for growing single-walled carbon nanotubes

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Carbon, ISSN: 0008-6223, Vol: 128, Page: 249-256

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Maoshuai He; Xiao Wang; Lili Zhang; Qianru Wu; Xiaojie Song; Alexander I. Chernov; Pavel V. Fedotov; Elena D. Obraztsova; Jani Sainio; Hua Jiang; Hongzhi Cui; Feng Ding; Esko Kauppinen Show More Hide
Elsevier BV
Chemistry; Materials Science; Catalyst; Single-walled carbon nanotube; Chirality selective; Reduction temperature; Solid solution; Anchoring effect
article description
The suitability of the Ni MgO catalyst as a catalyst in chiral-selective growth of single-walled carbon nanotubes (SWNTs) by chemical vapor deposition has been assessed. It reveals that catalyst calcination temperature plays an important role in affecting the catalyst performances. Using CO as the carbon precursor and a chemical vapor deposition reaction temperature of 600 °C, Ni MgO pre-calcined at 600 °C demonstrates the best performances in catalyzing the growth of SWNTs with predominant (6, 5) species. Systematic characterizations on catalysts calcinated at different temperatures indicate that Ni 2+ ions diffuse towards the interior of MgO matrix upon annealing. DFT-based calculations reveal that the binding energy between Ni 2+ and adjacent Ni(0) is larger than that between Mg 2+ and Ni (0), while Ni 2+ situated deep inside MgO has weak interactions with surface Ni atoms. This work highlights the importance of subsurface Ni 2+ in anchoring reduced surface Ni atom, which inhibits the aggregation of Ni particles and therefore, facilitates the growth of SWNTs with a narrow chirality distribution.