Topology Conversions of Non-Interpenetrated Metal–Organic Frameworks to Doubly Interpenetrated Metal–Organic Frameworks

Citation data:

Chemistry of Materials, ISSN: 0897-4756, Vol: 29, Issue: 9, Page: 3899-3907

Publication Year:
2017
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Repository URL:
http://scholarworks.unist.ac.kr/handle/201301/22292
DOI:
10.1021/acs.chemmater.6b05277
Author(s):
Jeong, Seok; Kim, Dongwook; Park, Jeongin; Shin, Sunyoung; Kim, Hyehyun; Jeong, Gyoung Hwa; Moon, Dohyun; Moon, Hoi Ri; Lah, Myoung Soo
Publisher(s):
American Chemical Society (ACS); AMER CHEMICAL SOC
Tags:
Chemistry; Chemical Engineering; Materials Science
article description
Non-interpenetrated three-dimensional (3D) metal-organic frameworks (MOFs) with both an interpenetration-favorable (3,5)-c hms topology and an interpenetration-unfavorable (3,5)-c gra topology are converted to doubly interpenetrated analogues with hms-c topology by thermal treatment, even in the absence of solvent. Depending on the conversion temperature and the properties of the pillaring ligand in the non-interpenetrated 3D MOF, which is based on two-dimensional sheets with 3-c hcb topology pillared by neutral ditopic linkers, the pillaring ligands in the interpenetrated MOFs produced are partially removed during the thermal conversions, leading to interpenetrated MOFs that simultaneously contain both micro- and mesopores.